2-[(4-Chlorobenzyl)iminomethyl]phenol
نویسندگان
چکیده
The title Schiff base compound, C(14)H(12)ClNO, was prepared from 4-chloro-benzyl-amine and salicyl-aldehyde. The mol-ecule is V-shaped: the dihedral angle between the aromatic rings is 67.51 (5)°. The rings are located on the opposite side of the C=N bond, giving an E configuration. An intra-molecular N-H⋯O hydrogen bond generates a S(6) ring. In the crystal structure, only weak non-classical C-H⋯O contacts are observed.
منابع مشابه
Crystal Structure of Schiff base Compound 2-[(2-chloro-4-nitrophenyl) iminomethyl] phenol
Single crystals of Schiff base compound 2-[(2-chloro-4-nitrophenyl) iminomethyl] phenol (1) were grown by the slow evaporation technique at room temperature. The crystal structure of the title compound was determined by single crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group P21, with two symmetry independent molecules. Intramolecular O-H···N hydr...
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We report the synthesis and magnetic characterisation of a series of planar [M₇] (M= Ni(II), Zn(II)) disc complexes [Ni₇(OH)₆(L₁)₆](NO₃)₂ (1), [Ni₇(OH)₆(L₁)₆](NO₃)₂·2MeOH (2), [Ni₇(OH)₆(L₁)₆](NO₃)₂·3MeNO₂ (3), [Ni₇(OH)₆(L₂)₆](NO₃)₂·2MeCN (4), [Zn₇(OH)₆(L₁)₆](NO₃)₂·2MeOH·H₂O (5) and [Zn₇(OH)₆(L₁)₆](NO₃)₂·3MeNO₂ (6) (where HL₁ = 2-iminomethyl-6-methoxy-phenol, HL₂ = 2-iminomethyl-4-bromo-6-methox...
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Two "end-off" compartmental ligands, 2-formyl-4-chloro-6-N-ethylmorpholine-iminomethyl-phenol (HL1) and 2-formyl-4-methyl-6-N-ethylpyrrolidine-iminomethyl-phenol (HL2) have been designed and three complexes of Mn(ii), one mono-, one di- and a polynuclear, namely Mn(L1)(SCN)2(H2O)] (), [Mn2(L1)(OAc)2](BPh4)] (), and [Mn2(L2)(OAc)2(dca)]n () have been synthesized and structurally characterized. V...
متن کامل2,4-Diiodo-6-{[4-(morpholin-4-yl)phenyl]iminomethyl}phenol
In the title compound, C(17)H(16)I(2)N(2)O(2), the two aromatic rings are almost coplanar [dihedral angle 2.57 (15)°]. The morpholine ring adopts a chair conformation. The mol-ecular structure is stabilized by an O-H⋯N hydrogen bond and the crystal packing exhibits weak inter-molecular C-H⋯O and π-π [centroid-to-centroid distances 3.663 (3)-4.073 (3) Å] inter-actions.
متن کامل3-Methoxy-2-[(E)-(4-methoxyphenyl)iminomethyl]phenol
The title compound, C(15)H(15)NO(3), adopts the enol-imine tautomeric form. The two rings are twisted with respect to each other, making a dihedral angle of 44.08 (5)°. The 3-methoxy-2-[(E)-(4-methoxyphenyl)-iminomethyl]phenol unit is almost planar, the largest deviation from the mean plane being 0.047 (2) Å. Such a planar conformation might be related to the occurrence of an intra-molecular O-...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010